substitute
/ˈsəb-stə-ˌtüt/
noun
a person or thing that takes the place or function of another
verb
to put or use in the place of another
to introduce (an atom or group) as a substituent; also : to alter (something, such as a compound) by introduction of a substituent
to take the place of : replace
noun
a teacher who teaches a class when the usual teacher is not available